This represents a localization of charge which is facilitated by the high electronegativity of fluorine. For instance, argon, krypton, and xenon form clathrates with hydroquinonebut helium and neon do not because they are too small or insufficiently polarizable to be retained.
The essential condition for their formation is that the guest noble gas atoms must be of appropriate size to fit in the cavities of the host crystal lattice.
Bonding results from the combination of a filled p-orbital from Xe with one half-filled p-orbital from each F atom, resulting in a filled bonding orbital, a filled non-bonding orbital, and an empty antibonding orbital. However, due to the high radioactivity and short half-life of radon isotopesonly a few fluorides and oxides of radon have been formed in practice.
The chemistry of the lighter ones, argon and helium, is still at an early stage, while a neon compound is yet to be identified. Xenon reacts with fluorine to form numerous xenon fluorides according to the following equations: This process is the basis for the potassium-argon dating method.
It can seep into buildings through cracks in their foundation and accumulate in areas that are not well ventilated.
Under extreme conditions, krypton reacts with fluorine to form KrF2 according to the following equation: Most of the helium in the universe was formed during Big Bang nucleosynthesisbut the amount of helium is steadily increasing due to the fusion of hydrogen in stellar nucleosynthesis and, to a very slight degree, the alpha decay of heavy elements.
These are compounds such as ArF and KrF that are stable only when in an excited electronic state ; some of them find application in excimer lasers. The clathratesfirst described in consist of a noble gas atom trapped within cavities of crystal lattices of certain organic and inorganic substances.
Bonding in such compounds can be explained using a three-center four-electron bond model. The highest occupied molecular orbital is localized on the two terminal atoms.
Due to its high radioactivity, radon presents a significant health hazard; it is implicated in an estimated 21, lung cancer deaths per year in the United States alone. Occurrence and production[ edit ] The abundances of the noble gases in the universe decrease as their atomic numbers increase.
In addition to the compounds where a noble gas atom is involved in a covalent bondnoble gases also form non-covalent compounds. For example, bonding in XeF 2 is described by a set of three molecular orbitals MOs derived from p-orbitals on each atom.History.
Noble gas is translated from the German noun Edelgas, first used in by Hugo Erdmann to indicate their extremely low level of reactivity. The name makes an analogy to the term "noble metals", which also have low killarney10mile.com noble gases have also been referred to as inert gases, but this label is deprecated as many noble gas .Download